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The laboratory was established in 1954. Professor Dmitry Nikolaevich Kursanov, being the corresponding member of the USSR Academy of Sciences was the founder of the laboratory.
Research area:
Synthesis and studies of the structure and reactivity of organometallic compounds under the conditions of ion and radical ion reactions in condensed and gas phases. The engineering aspect of these studies consists in the revelation of the practically important properties of the synthesized compounds (biological activity, catalytic, and photochromic properties, and others).
Grants:
1. The Purpose-oriented programme of the Presidium of the RAS “Supporting young scientists” in a section “Support in the activity of basic divisions and other educational structures».
Heads of the basic divisions – Prof. Yu.S. Nekrasov, Dr.Sc. and Prof. L.V. Snegur, Dr.Sc.
2. A grant «Polyfunctional monomeric and dendritic cymantrene derivatives in asymmetric synthesis and photochromic systems» under the Programme of the Presidium of the Russian Academy of Sciences “Development of methods for preparing chemical compounds and creation of new materials”;
Project manager - Yu.S. Nekrasov.
3. A grant “Development of antitumor preparations based on ferrocene derivatives” under the Programme of the Presidium of the Russian Academy of Sciences “Basic sciences for medicine”;
Project manager - Yu.S. Nekrasov.
4. A grant «Directed synthesis of new ferrocene derivatives having antitumor activity» under the Programme No. 10 of the Department of Chemistry and Material Sciences “Biomolecular and Medicinal Chemistry”;
Project manager - Yu.S. Nekrasov.
5. A grant RFFR № 09-03-00535 «Experimental and theoretical study on the mechanisms of metallocene ion-formation under the conditions of electrospray ionization».
Project manager - Yu.S. Nekrasov.
Recent publications:
1. Т.Ю.Орлова, Ю.С.Некрасов, П.В.Петровский, М.Г.Езерницкая, З.А.Старикова, О.Л.Лепендина. Синтез и строение комплексов h5-C5H5Cl(CO)2W-h1,h5-(PPh2)C5H4(CO)2Fe-h1,h5-C5H4Mn(CO)3 и MeSi[-C5H4(CO)2Fe-h1,h5-C5H4Mn(CO)2PPh3]3 Изв. РАН, сер.хим. 2008, №1, 60.
2. L.V. Snegur, Yu.S. Nekrasov, N.S. Sergeeva, Zh.V. Zhilina, V.V Gumenyuk, ZA. Starikova, A.A. Simenel, N.B. Morozova, I.K. Sviridova, and V.N. Babin. “Ferrocenylalkyl Azoles. Bioactivity, Synthesis, Structure”. Appl. Organomet. Chem. 2008, 22, 139-147.
3. Telegina L. N., Ezernitskaya M. G., Godovikov I. A., Babievskii K. K., Lokshin B. V., Strelkova T. V., Borisov Y. A., Loim N. M. Investigation of Photochemical Behaviour of Tricarbonyl Cyclopentadienylmanganese Derivatives with Carbamate Groups. Eur. J. Inorg. Chem. 2009, I. 24, p. 3636-36433.
4. Yury I., Lyakhovetsky, Vasily V. Bashilov, Tatyana V. Efanova, Elena A. Shilova, Viatcheslav I. Sokolov, Yuri S. Nekrasov, Roger Taylor. Trifluoromethylation of C60 and C70 with mercury(II) trifluoroacetate. Fullerenes, Nanotubes and Carbon Nanostructures, 17, 85-98, 2009.
5. Yu.S. Nekrasov, Yu.A. Borisov, R.S. Skazov, A.A. Simenel, L.V. Snegur, Yu.A. Belousov, A.N. Rodionov. The reactivity of ferrocenylalkyl azoles under the conditions of electrospray ionization. Journal of Organometallic Chemistry, Volume 694, Issue 12, 2009, P. 1807-1812.
6. Ю.С. Некрасов, Ю.А. Борисов, Р.С. Сказов, А.Н.Родионов, А.А. Сименел, Ю.А.Белоусов. О механизме окисления ферроцена в условиях ионизации электрораспылением. Изв. РАН, сер.хим. 2009, №7, 1476-1478.
7. Yury I. Lyakhovetsky, Elena A. Shilova, Vasily V. Bashilov, Viatcheslav I. Sokolov, Yuri S. Nekrasov, and Boris L. Tumanskii. Homolytic Reactive Mass spectrometry of Fullerenes: Interaction of C60 and C70 with Organo- and Organoelement Mercurials in the Electron Impact Ion Source of a Mass Spectrometer; EPR, CIDEP, and MS Studies of Several Analogous Reactions of C60 Performed in solution. J. Phys. Chem. A 2009, 113, 13700–13710.
8. А.Н. Родионов, А.А. Сименел, Ю.С. Некрасов, В.В. Качала, Е.Ю. Осипова, К.Я. Жеребкер. Восстановительное аминирование ферроценилформилпиразолов. Изв. РАН, сер.хим. 2010, №2,
9. A.A. Simenel, E.A. Morozova, L.V. Snegur, S.I. Zykova, V.V. Kachala, L.A. Ostrovskaya, N.V. Bluchterova, M.M. Fomina, Simple route to ferrocenylalkyl nucleobases. Antitumor activity in vivo, Appl. Organomet. Chem. 2009, 23, 219-224.
10. Т.Ю.Орлова, Ю.С.Некрасов. Биядерные комплексы «лестничного» типа как «строительные блоки» для синтеза новых полиядерных систем. Изв. РАН, сер.хим. 2010, № 5, 853-860