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Subjects of investigations:
Development of the organophosphorus synthesis methodology including “green chemistry” procedures (synthesis in ionic liquids, water and/or under phase catalysis conditions) resulting in organophosphorus compounds of practical importance having bioactivity or complexing properties; investigations of reaction peculiarities, stereochemistry and mechanisms of new type rearrangements, polymerizations, intra- and intermolecular cyclizations in the series of functionalized organophosphorus compounds; coordination chemistry of oligodentate ligands and investigation of catalytic, luminescent and magnetochemical properties of metal complexes.
Current grants:
1. Grant RBRF 08-03-00508 “Complex formation peculiarities of hybride phosphorus-containing pincer ligands of new types with platinum group metals: structure, catalytical activity and luminescent properties of metal complexes”
2. Program Division of Chemical Sciences and Material No. 9 “Medicinal and biomolecular chemistry” (coordinator - academician N.S. Zefirov), project “Biologically active omega-aminophosphonates and the strategy of their synthesis”
3. Program of the Presidium of RAS P18 “Development of the organic synthesis methodology and synthesis of compounds having valuable applied properties” (coordinator- academician V.A. Tartakovskii, Leader of the program - academician Yu. N. Bubnov), project “Methods of synthesis of novel phosphorus-nitrogen ligands”
4. Grant of the President of Russian Federation for young scientists MK-425.2010.3 “Water and ionic liquids as alternative solvents in nucleophilic addition reactions of organophopsphorus compounds having multiple bonds” Leader - E. V. Matveeva (2010-2011).
Main publications 2008-2011 :
1. M. I. Kabachnik. Chemistry of the Organophosphorus compounds. Selected Proceedings, in 3 volumes (publishers М.: NAUKA, 2008-2009).
2. E. V. Sharova, O. I. Artyushin, A. S. Shaplov, G.V.Myasoedova, I. L. Odinets. A Novel Facile Synthesis of Carbamoylmethylphosphine oxides in Ionic liquids. Tetrahedron Lett., 2008, 49, 1641-1644
3. V.A. Kozlov, D.V. Aleksanyan, Yu.V. Nelyubina, K.A. Lyssenko, E.I.Gutsul, L.N.Puntus, A.A.Vasil’ev, P.V. Petrovskii, I.L. Odinets. Cyclopalladated Complexes of 3-Thiophosphorylbenzoic Acid Thioamides - Hybrid Pincer Ligands of a New Type. Synthesis, Catalytic activity and Photophysical properties. Organometallics, 2008, 27(16), 4062-4070.
4. E. V. Matveeva, P. V. Petrovskii, I. L. Odinets. Efficient synthesis of racemic b-aminophosphonates via aza-Michael reaction in water. Tetrahedron Lett., 2008, 49, 6129-6133.
5. Irina L. Odinets, Oleg. I. Artyushin, Nikolay Shevchenko, Pavel V. Petrovskii, Valentin G. Nenaidenko, Gerd-Volker Röschenthaler. Efficient synthesis of substituted cyclic a-aminophosphonates. Synthesis, 2009, 4, 577-582.
6. Michael V.Makarov, Ekaterina Yu. Rybalkina, Gerd-Volker Röschenthaler, Kurt W. Short, Tatiana V. Timofeeva, Irina L.Odinets. Design, cytotoxic and fluorescent properties of novel N-phosphorylalkyl substituted E,E-3,5-bis(arylidene)piperid-4-ones. Eur.J.Med.Chem., 2009, 44(5), 2135-2144.
7. I.L. Odinets, O.I. Artyushin, S.N.Osipov, G.-V. Röschenthaler, “Propargyl Substituted Phosphonocarboxylates. Efficient Synthesis and Application for Click Chemistry”. Synthesis, 2009, 21, 3579-3588.
8. I.M. Aladzheva, O.V. Bykhovskaya, Y.V.Nelyubina, A.A. Korlyukov, P.V. Petrovskii, I.L. Odinets. Facile one-pot synthesis and X-ray characterization of N-(thio)phosphoryl-2-oxo-1,2-azaphospholanes: first example of cyclic O,O- and O,S-bidentate ligands with the P-N-P backbone, Synthesis, 2010, 613-618.
9. I.L. Odinets, E.V. Sharova, O.I.Artyshin, K.A. Lyssenko, Yu.V. Nelyubina, G.V.Мyasoedova, N.P.Molochnikova, E.A.Zakharchenro. Novel class of functionalized ionic liquids with grafted CMPO-moieties for actinides and rare-earth elements recovery. Dalton Trans., 2010, 39, 4170 – 4178.
10. V.A. Kozlov, D.V. Aleksanyan, Yu.V. Nelyubina, K.A. Lyssenko, P.V. Petrovskii, I.L. Odinets. Cyclopalladation of meta-Diphenylthiophosphoryloxybenzaldimines: NCS and unexpected NCO 5,6-Membered Pincer Palladium Complexes. Organometallics, 2010, 29(9), 2054-2062.
11. I. L. Odinets, E.V. Matveeva. “Green” solvents in organophosphorus synthesis (review). Current Organic Chem., 2010, 14(12), 1171-1184.
12. V. A. Kozlov, D.V. Aleksanyan, Yu.V. Nelyubina, K.A. Lyssenko, P.V. Petrovskii, A.A. Vasil’ev, I.L. Odinets. Hybrid Thiophosphoryl-Benzothiazole Palladium SCN-Pincer Complexes: Synthesis and Effect of Structure Modifications on Catalytic Performance in the Suzuki cross-coupling. Organometallics, 2011; 30(11), 2920-2932
13. I. M. Aladzheva, O.V. Bykhovskaya, Y.V. Nelyubina, P.V. Petrovskii, Z.S. Klemenkova, I.L. Odinets Uranium Complexes of cyclic O,O-bidentate ligands with the P-N-P backbone. Inorg.Chim.Acta, 2011, 373, 130-136